How to balance the flash with the ambiance
This is a general approach to the technique, you can start with any aperture or shutter speed, just remember the max flash sync speed:
- Set your ISO to the lowest value for highest image quality if you are shooting outdoor or in a bright location. Up this value if you are in a low light location.
- Find the exposure for the ambiance. For this you can either use the camera metering indicator thru the viewfinder or take a shot in Aperture Priority and use the same settings back in Manual Mode.
- Under-expose the ambiance by 2 stops, so when we'll bring in the flash onto the subject he/she will stands out.
- Bring the flash in and get an exposure for the flash.
- Chimp to verify your histogram and judge the flash/ambiance ratio.
- Adjust the shutter speed if you want to change the intensity of the ambiance.
- Adjust the aperture if you want to change the exposure for the flash. Then dial the same value to the shutter speed, in the opposite way, to compensate the ambiance.